The derivates of 1,2,4,3-triazaphospholes can exist in several different isomeric forms depending on the type of substitution. Forms 1 and 2 were prepared using methods described in the literature (1) (3) by action of hydrazine on imited where two forms of amidrazones A and B were obtained which react with tris (dimethyl-amino) phosphine to give an important quantity of 1 accompagned by quantity of 2 and some times only 1. In this work, we are describing a new method giving a better quantity of 2 and particulary when the type of substitutions were Ph. Ph. We acced to the diphenyl-1,5 triazaphosphole-1,2,4,3 which coudn't be obtained by Y. Charbonnel methods (1) (3). The 1,5 disubstituted-1,2,4,3-triazaphospholes react with organomagnesium halides like the 2,5 disubstituted homologues. We are giving here the results of this comparative study.
M. Haddad, M.T. Boisdon, J. Barrans
Pages 75-88
Action of the two equivalent of the L.D.A. on ethyl benzylhydroximate leads to the corresponding dilithiohydroximate. The latter reacts with carboxylic esters and carbonated derivatives (aldehydes and ketones) to give after hydrolysis, the hydroxyled hydroximates which are treated with concentrated sulfuric acid, thus they are transformed accordingly into 1,2-oxazoles or 4,5-dihydro 1,2-oxazoles.
H. M’rabet, A. Bel Hadj Amor, B. Baccar
Pages 89-96
We synthesised eight new organostannic fluorine derivatives by different synthetic ways. The new products had expected structure proved by NMR spectroscopy and elemental analysis.
F. Meganem, A Belhadj Yahia
Pages 97-103
A precipitate phase Na3MgH(PO4)2 was obtained when salt phosphate solution containing magnesium was concentrated under different water pressures. This phase was not effected by the water pressure changes in the range of 0.3-2 atm. However, an important change was observed in the morphology and the crystallinity.
M. Ben Amor, M. Aoun, S.S. Romdhane
Pages 105-112
Small angle X-ray scattering under synchrotron radiation is a new method which allows on to calculate for each clay sample, the statistical distribution of the thickness of the layers and the average number of the individual layer which forms a particle. Hectorite, montmorillonite from Wyoming, montmorillonite from Camp Berteaux, nontronite and vermiculite have been studied by this technique. The following results were obtained :
- Parameters influencing the number of the individual layer and the swelling are the layer charges independently on the nature of the exchangeable cations.
- Swelling tends to be low in clay with tetrahedrally charged.
- Interparticle water is three or four times higher than in interlayer water.
F. Turki
Pages 113-124
The paper proposes a fonctionnement of a fixed bed electrochemical reactor. The limiting current technique is used to obtain the liquid - solid mass transfer coefficient. The porous electrode is made of copper particles which are percolated by a dilute solution of Cu++ ions in a sulfuric acid medium. We found a correlation between the Reynolds number Re and the Sherwood number Sh : Sh = 2,1 Re0,35 Sc0,33. This correlation is compared with empirical ones obtained by several authors and is in good agreement with them.
M. Benzina. S. Gabsi, G. Lacoste
Pages 125-140